Laboratoire Léon Brillouin

UMR12 CEA-CNRS, Bât. 563 CEA Saclay

91191 Gif sur Yvette Cedex, France

+33-169085241 llb-sec@cea.fr

BD diffusons les neutrons

31 juillet 2017
Three-legged 2,2′-bipyridine monomer at the air/water interface: monolayer structure and reactions with Ni(II) ions from the subphase
logo_tutelle logo_tutelle 
Three-legged 2,2′-bipyridine monomer at the air/water interface: monolayer structure and reactions with Ni(II) ions from the subphase

Air/water reflectivity curves

Three-legged 2,2′-bipyridine monomer at the air/water interface: monolayer structure and reactions with Ni(II) ions from the subphase,
Wenyang Dai, Lay-Theng Lee, Andri Schütz, Benjamin Zelenay, Zhikun Zheng, Andreas Borgschulte, Max Döbeli, Wasim Abuillan, Oleg V. Konovalov, Motomu Tanaka and A. Dieter Schlüter, Langmuir, 2017, 33 (7),  1646

The behavior of compound 2 [1,3,5-tri(2,2′-bipyridin-5-yl)benzene] with three bipyridine units arranged in a star geometry is investigated in the presence and absence of Ni(ClO4)2. Its properties at the air–water interface as well as after transfer onto a solid substrate are studied by several techniques including Brewster angle microscopy, X-ray reflectivity, neutron reflectivity, X-ray photoelectron spectroscopy, Rutherford backscattering spectrometry, and atomic force microscopy combined with optical microscopy. It is found that compound 2 within the monolayers formed stays almost vertical at the interface and that at high Ni2+/2 (Ni2+/2 = 4000, 20′000) ratios two of the three bipyridine units of 2 are complexed, resulting in supramolecular sheets that are likely composed of arrays of linear metal–organic complexation polymers.

 
#2767 - Màj : 31/07/2017

Retour en haut